Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands† †Electronic supplementary information (ESI) available: Detailed experimental procedures, and spectral data for all compounds, including scanned images of 1H and 13C NMR spectra. See DOI: 10.1039/c7sc00071e Click here for additional data file.

Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands.

A Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes has been developed. Acyl aminocyclopropanes were reacted with hydrosilanes in the presence of Rh catalysts to afford ring-opened hydrosilylated adducts through carbon-carbon (C-C) bond cleavage of the cyclopropane ring. The regioselectivity of the addition of silanes (linear or branched) can be switched by changing the mon...

Stereoselective Lewis base catalyzed formal 1,3-dipolar cycloaddition of azomethine imines with mixed anhydrides† †Electronic supplementary information (ESI) available: Detailed experimental procedures, and spectral data for all compounds, including scanned images of 1H and 13C NMR spectra. CCDC 1019046. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02612h

Copper-catalyzed direct alkylation of heteroarenes† †Electronic supplementary information (ESI) available: Experimental procedures, characterization and copies of 1H and 13C NMR spectra for all new compounds. See DOI: 10.1039/c6sc05622a Click here for additional data file.

Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile† †Electronic supplementary information (ESI) available: Experimental details including characterization data, copies of 1H, 13C NMR and NOESY spectra. See DOI: 10.1039/c5sc04066c Click here for additional data file.

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Enantioselective bifunctional iminophosphorane catalyzed sulfa-Michael addition of alkyl thiols to unactivated β-substituted-α,β-unsaturated esters† †Electronic supplementary information (ESI) available: Experimental procedures, spectroscopic data, copies of 1H and 13C NMR spectra and HPLC and GC chromatograms. See DOI: 10.1039/c6sc02878k Click here for additional data file.